Structural investigations of silver (I) and copper (I) complexes with neutral nitrogen (N4) donor ligands: x-ray crystal and molecular structure of the dimer [Ag2 {. mu.-(R) …
GC Van Stein, G Van Koten, K Vrieze…
文献索引：Stein, Gerard C. van; Koten, Gerard van; Vrieze, Kees; Brevard, Christian; Spek, Anthony L. Journal of the American Chemical Society, 1984 , vol. 106, # 16 p. 4486 - 4492
Abstract: The reactions of the neutral N4 donor system (R, S)-1, 2-(6-R-py-2-CH= N), Cy (R= H or Me, Cy= cyclohexane) with [M (O, SCF,)](M= Ag (1) or Cu (1)) yielded ionic complexes, consisting of a dinuclear [M2 (N4) 2] 2+ dication and O, SCF,-monoanions. An X-ray crystallographic study defined the molecular structure of [Ag2 (p-(R, 59-1, 2-(py-2-CH= N) 2Cy) 2](O, SCF,), as monoclinic, space group P2'/c, a= 10.412 (2) A, b,= 33.310 (8) A, c= ...
