Green Chemistry

Minimisation of E-Factor in the synthesis of N-hydroxylamines: the role of silver (I)-based coordination polymers

M Sheykhan, ZR Ranjbar, A Morsali, A Heydari

文献索引：Sheykhan, Mehdi; Rashidi Ranjbar, Zohreh; Morsali, Ali; Heydari, Akbar Green Chemistry, 2012 , vol. 14, # 7 p. 1971 - 1978

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被引用次数: 9

摘要

Among four different 2-D polymeric silver (I)–bpfb assemblies synthesized,[Ag (μ-bpfb)(N3)] n (4c) having an azide anion was shown to be the best catalyst for the partial oxidation of primary amines to N-monoalkylhydroxylamines with urea hydrogen peroxide (UHP). The method has supplied the minimum E-Factor (which is in the range for bulk chemicals) amongst all of the presented methods. More importantly, the catalyst could be easily ...