Metal-assisted reactions. Part 29. 1 Structure and hydrogenolysis of C–N bonds in derivatives of aromatic amines. Bond length and electronegativity changes from X- …

…, CJ Dillon, CFC Fonseca, RAW Johnstone

文献索引：Brigas, Amadeu F.; Clegg, William; Dillon, Christopher J.; Fonseca, Custodia F.C.; Johnstone, Robert A.W. Journal of the Chemical Society. Perkin Transactions 2, 2001 , # 8 p. 1315 - 1324

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被引用次数: 2

摘要

Pseudosaccharyl and phenyltetrazolyl derivatives 1–6 were prepared with the aim of weakening the originally strong C–N bond in aromatic amines and facilitating its hydrogenolysis. Structural analyses of the amines 1–6 by 1H and 13C NMR spectroscopy and X-ray diffraction methods have revealed major changes in C–N bond lengths on derivatization as a result of changes in conjugation. These changes are discussed in ...