Dicyclooctabiphenylene. Synthesis and properties

CF Wilcox Jr, EN Farley

文献索引：Wilcox, Charles F.; Farley, Erik N. Journal of the American Chemical Society, 1984 , vol. 106, # 23 p. 7195 - 7200

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被引用次数: 36

摘要

Abstract: The synthesis and properties of the “antiaromatic” hydrocarbon dicycloocta [1, 2, 3, 4-def: 1', 2', 3', 4'-jkl] biphenylene (1) are described. The observed electronic and 'H NMR spectra of 1 agree well with previous predictions. The series of polycycles consisting of biphenylene (3), cycloocta [defl biphenylene (Z), and dicycloocta [dejjkl] biphenylene (1) is examined in terms of resonance energy and qualitative aromaticity models.