Journal of the American Chemical Society

The reaction of ketones with iodine and thiourea1

LC King, RJ Hlavacek

文献索引：King; Hlavacek Journal of the American Chemical Society, 1950 , vol. 72, p. 3722

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被引用次数: 109

摘要

Summary A study has been made of the Schmidt reaction on a series of $ xzra-substituted benzophenones, a series of phenyl alkyl ketones, and two unsaturated aralkyl ketones. The ratios of the two isomeric amides formed in each case are nearly independent of para- substituents, but are greatly affected by changes in the steric environment of the carbonyl group. These observations are correlated with existing theory.