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Chemoselective thioacetalization and transthioacetalization of carbonyl compounds catalyzed by immobilized scandium (III) triflate in ionic liquids

A Kamal, G Chouhan

文献索引:Kamal, Ahmed; Chouhan, Gagan Tetrahedron Letters, 2003 , vol. 44, # 16 p. 3337 - 3340

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被引用次数: 44

摘要

Immobilized scandium triflate [Sc (OTf) 3] in ionic liquids has been found to be an extremely efficient and recyclable catalyst for the thioacetalization and transthioacetalization of both aromatic and aliphatic aldehydes. Significant rate acceleration and chemoselectivity was achieved by employing this catalytic system.