Applied Catalysis A: General

Environmentally-benign palladium (II)-exchanged hydroxyapatite-catalyzed allylic alkylation of allyl methyl carbonate in water

Y Masuyama, Y Nakajima, J Okabe

文献索引：Masuyama, Yoshiro; Nakajima, Yukiko; Okabe, Jun Applied Catalysis A: General, 2010 , vol. 387, # 1-2 p. 107 - 112

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被引用次数: 11

摘要

Palladium (II)-exchanged hydroxyapatite (PdHAP; for example, PdHAP-B has a Pd/Ca ratio= ca 1/200) was prepared by ion-exchanging with Ca2+ from calcined hydroxyapatite and Pd (NO3) 2 in water at 70° C for 24h. The ion-exchange was revealed by inductively coupled plasma analysis; Pd2+ was almost absent in any filtrate that included over 1.6 equimolar amounts of Ca2+ relative to the amount of Pd2+ consumed. The PdHAP (1mol% Pd) ...