Molten salt catalyzed transfer hydrogenation of polycyclic aromatic hydrocarbons. Selective hydrogenation of anthracene and naphthacene by tetralin in molten …

AC Buchanan III, AS Dworkin…

文献索引：Buchanan, A. C.; Dworkin, A. S.; Smith, G. P. Journal of Organic Chemistry, 1982 , vol. 47, # 4 p. 603 - 607

全文：HTML全文

被引用次数: 12

摘要

Anthracene and naphthacene are selectively hydrogenated by tetralin to 9, 10- dihydroanthracene and 5, 12-dihydronaphthacene, respectively, in a reaction that is catalyzed by molten SbC13 at 80 OC. In situ lH NMR studies indicate that under similar conditions, phenanthrene and pyrene do not react, while perylene is partially oxidized to a persistent radical cation. For the tetralin transfer hydrogenation of anthracene and ...