Synthesis of C, N-diaryl nitrones from the reduction of nitroarene with aromatic aldehydes promoted by metallic samarium

X Jia, D Li, Q Huang, L Zhu, J Li

文献索引：Jia, Xueshun; Li, Dafeng; Huang, Qing; Zhu, Li; Li, Jian Journal of Chemical Research, 2007 , # 5 p. 308 - 309

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被引用次数: 2

摘要

The use of metallic samarium as a reducing agent in organic synthesis has recently attracted attention.5 This is due to the fact that metallic samarium is stable in air and has strong reducing power (Sm3+/Sm = 2.41V). It is also cheap and easy to handle. Recently, we have reported the reduction and the C-acetylation of BaylisHillman adducts as well as the acylation of alcohols with acyl chlorides promoted by metallic samarium.6 We now report a facile reductive ...