Russian journal of organic chemistry

Dual Mechanism of Enamine-enamine Rearrangement of 1, 3-diaryl-3-(1-imidazolyl) propen-2-ones

MA Rekhter, B ARekhter

文献索引：Rekhter Russian Journal of Organic Chemistry, 2002 , vol. 38, # 4 p. 593 - 594

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被引用次数: 2

摘要

Abstract The formation of 1, 3-diaryl-3-(1-imidazolyl) propen-1, 3-diol that is an intermediate of enamine-enamine rearrangement of 1, 3-diaryl-3-(1-imidazolyl) propen-1-ones constitutes the key stage of the dual mechanism of the rearrangement proper. The reaction of 1, 3-diaryl-2, 3-dibromopropan-1-ones with a primary amine provides 1, 3-diaryl-3- iminopropan-1-ones as a result of enamine-imine prototropic rearrangement.