Bulletin of the Chemical Society of Japan

Total Syntheses of (±)-Aerothionin,(±)-Homoaerothionin, and (±)-Aerophobin-1

S Nishiyama, S Yamamura

文献索引：Nishiyama; Yamamura Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 12 p. 3453 - 3456

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被引用次数: 66

摘要

(±)-Aerothionin,(±)-homoaerothionin, and (±)-aerophobin-1 have been successfully synthesized using phenolic oxidation of the methyl pyruvate oxime derivative with thallium (III) trifluoroacetate as a key step. The stereostructure of aerophobin-2 has been also established by comparison of the 1 H NMR spectrum with those of related compounds.