Synthese et structure d'oxydes et dioxydes de phosphines tertiaires

N Platzer, F Dardoise, W Bergeret…

文献索引：Platzer, Nicole; Dardoise, Francois; Bergeret, Wilfrid; Gautier, Jean Claude; Raynal, Serge Phosphorus and Sulfur and the Related Elements, 1986 , vol. 27, p. 275 - 284

全文：HTML全文

被引用次数: 1

摘要

Abstract Tertiary phosphine oxides have been prepared in excellent yield from primary alkyl halides and dihalides or aromatic halides and activated sodium phosphinates obtained by reaction of dialkyl phosphine oxides with complex bases (NaNH2/t BuONa). We have studied by 13C NMR the structure of these compounds. We have reported more particularly the influence of carbon atoms number between the two phosphorus in the case of ...