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Novel cryptands containing thiourea units as a part of the macrocyclic framework

NG Lukyanenko, TI Kirichenko…

文献索引:Lukyanenko, Nikolay G.; Kirichenko, Tatiana I.; Scherbakov, Sergey V. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 21 p. 2347 - 2351

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被引用次数: 15

摘要

Alkylation of diaza-18-crown-6 by N-substituted phthalimides having a terminal halogen in the substituent, and subsequent product interaction with hydrazine hydrate and acid hydrolysis gave corresponding N, N′-disubstituted diaza-18-crown-6 compounds with terminal primary amino groups in the side chains. The reaction of these compounds with carbon disulfide or with appropriate bis [oligo (ethyleneoxy)] isothiocyanates afforded a ...