Cleavage of CC double bonds by a novel cycloaddition–cycloreversion sequence

J Kalvoda, H Kaufmann

文献索引：Kalvoda,J.; Kaufmann,H. Journal of the Chemical Society, Chemical Communications, 1976 , p. 209 - 210

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被引用次数: 2

摘要

CC-double bonds are cleaved with simultaneous generation of a carbonyl compound and a nitrile by a sequence involving 1, 3 dipolar addition of ethoxycarbonylformonitrile oxide to the olefin, hydrolysis of the 3-ethoxycarbonyl-isoxazoline which is formed to the free acid, and thermal decarboxylation.