Novel oxidative nitrogen to carbon rearrangement found in the conversion of anilines to benzaldoximes by treating with HCHO/H 2 O 2

…, K Kapuriya, NM Dodia, YW Lin, R Kakadiya, CT Wu…

文献索引：Kapuriya, Naval; Kapuriya, Kalpana; Dodia, Narsinh M.; Lin, Yi-Wen; Kakadiya, Rajesh; Wu, Chao-Ting; Chen, Ching-Huang; Naliapara, Yogesh; Su, Tsann-Long Tetrahedron Letters, 2008 , vol. 49, # 18 p. 2886 - 2890

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被引用次数: 5

摘要

Novel rearrangement was found by reacting anilines with HCHO/H2O2 resulting in the synthesis of various benzaldoximes. The mechanism of the rearrangement is proposed and suggested that the rearrangement might proceed via unstable N-phenyloxazirane intermediate followed by the transfer of aryl moiety from nitrogen to carbon atom leading to the formation of benzaldoxime.