First synthesis of a 1, 2, 3, 4-tetrazine

…, T Itoh, K Yamaguchi, A Ohsawa

文献索引：Kaihoh, Terumitsu; Itoh, Takashi; Yamaguchi, Kentaro; Ohsawa, Akio Journal of the Chemical Society, Chemical Communications, 1988 , # 24 p. 1608 - 1609

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被引用次数: 11

摘要

Ph -iNxN%Y \ / N NGN P h - "1 'N/ I N"2 (3) ... 7 Compound (3) was obtained along with the 2-amino isomer by amination of 5-phenyl[l,2,3]triazolo[4,5-d]-1,2,3-triazole6 ... $ A similar method was used for the synthesis of 1,2,3-triazines by oxidation of N-aminopyrazoles.8 ... Figure 1. X-Ray crystal structure of (2). ORTEP view showing the atom numbering figure. Important parameters: N(l)-N(2) 1.359, N(2)-N(3) 1.299, N(2)-C(lO) 1.476, N(3)-C(8) 1.351, N(l)-C(9) ...