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Alkylations of Mono-and Dipotassio-2, 3, 3-triphenylpropionitrile. Equilibrium Factor in Benzhydrylations of 1, 2-Dianions. Dehydrocyanation1

WG Kofron, WR Dunnavant…

文献索引:Kofron,W.G. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 2737 - 2741

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被引用次数: 4

摘要

Alkylations of 2, 3, 3-triphenylpropionitIile (I) through its monocarbanion to form the corresponding a-derivatives were effected with such diverse halides as n-butyl and benshydryl halides in liquid ammonia. Alkylation of I through its dicarbanion to afford the p- derivative was realized with the butyl halide but not with the benzhydryl halide. The reaction with the latter halide gave mainly 2, 3, 3-triphenylacrylonitrile and tetraphenylethane. A ...