Electrochemical oxidation of the 2, 3-diphenylindole system. Elucidation of the coupling position and analogous behavior for the N-substituted system

GT Cheek, RF Nelson, JM Bobbitt…

文献索引：Cheek, Graham T.; Nelson, Robert F.; Bobbitt, James M.; Scola, Paul M. Journal of Organic Chemistry, 1987 , vol. 52, # 23 p. 5277 - 5280

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被引用次数: 3

摘要

a product 5 containing only one deuterium rather than two as required by 6. This structure proof is similar to our work on the oxidative coupling of 1, 2, 3, 4-tetrahydrocarbazole to give the corresponding dimer3 and relies on 13C and 2D NMR as well as mass spectrometry of the relevant compounds. In the present case, the deuteriated monomer 2 was prepared by catalytic deuteriation of the known 6-chlore2, 3-diphenylindole (3) 4 in CH30D/KOCH3 ...