Tetrahedron Letters

A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes

S Gagneur, H Makabe, E Negishi

文献索引：Gagneur, Sebastien; Makabe, Hidefumi; Negishi, Ei-Ichi Tetrahedron Letters, 2001 , vol. 42, # 5 p. 785 - 787

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被引用次数: 9

摘要

Hydrogen transfer hydroalumination of terminal alkenes and dienes can be achieved with 1.1 equiv. of (i-Bu) 3 Al and catalytic amounts of Cl 2 Pd(PPh 3 ) 2 and other late transition metal complexes containing Co, Rh, Ni, and Pt at ambient temperature in high yields. ... Hydrogen transfer hydroalumination of terminal alkenes and dienes can be achieved with 1.1 equiv. of (i-Bu) 3 Al and catalytic amounts of Cl 2 Pd(PPh 3 ) 2 and other late transition metal ...