Tetrahedron Letters

Zinc-catalyzed aerobic oxidation of benzoins and its extension to enantioselective oxidation

P Muthupandi, G Sekar

文献索引：Muthupandi, Pandi; Sekar, Govindasamy Tetrahedron Letters, 2011 , vol. 52, # 6 p. 692 - 695

被引用次数: 20

摘要

Zn (II)–DABCO complex is used as an efficient catalyst for the aerobic oxidation of benzoins to benzils in the presence of molecular oxygen. Usage of chiral zinc complex as catalyst resulted in enantioselective oxidative kinetic resolution of racemic benzoin to yield enantiomerically enriched benzoins.

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