Tetrahedron Letters

Oxidations of alkenes with hypervalent iodine reagents: an alternative ozonolysis of phenyl substituted alkenes and allylic oxidation of unsubstituted cyclic alkenes

U Atmaca, HK Usanmaz, M Çelik

文献索引：Atmaca, Ufuk; Usanmaz, Hande K.; Celik, Murat Tetrahedron Letters, 2014 , vol. 55, # 14 p. 2230 - 2232

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被引用次数: 5

摘要

C double bonds with a phenyl substituent can be cleaved with iodylbenzene and iodosylbenzene to give carbonyl compounds. It is believed that the reactions occur via a radical pathway. The allylic oxidation of cyclic alkenes lacking a phenyl substituent was achieved in acetonitrile/water mixture (3: 1) also using iodylbenzene and iodosylbenzene.