Abstract 1-Benzyl-5, 6-dihydro-1H, 2, 3-triazolo [4, 5-d] pyridazine-4, 7-dione (1) by oxidation with lead tetraacetate afforded the corresponding triazolopyridazine-4, 7-dione 2 as the intermediate, which was trapped with several dienes giving the hetero-Diels-Alder adducts 3 in good yields. The structure of the cycloadduct 3a was determined by X-ray analysis.