Ionic??Liquid??Influenced Expeditious and Stereoselective Synthesis of Olefins

SV Bhilare, NB Darvatkar, AR Deorukhkar…

文献索引：Bhilare, Sachin V.; Darvatkar, Nitin B.; Deorukhkar, Amol R.; Rasalkar, Meghana S.; Salunkhe, Manikrao M. Synthetic Communications, 2007 , vol. 37, # 18 p. 3111 - 3117

全文：HTML全文

被引用次数: 10

摘要

Abstract 1??Butyl??3??methylimidazolium chloroaluminate,[bmim] Cl·. AlCl3 (molar fraction, N= 0.67), ionic liquid has been used in combination with metallic Zn for the reductive coupling of carbonyl compounds to synthesize symmetrical olefins, with the Z??isomer formed predominantly. The ionic liquid played a dual role of Lewis acid catalyst and solvent.