Tetrahedron letters

Photooxygenation of 1, ω-bis (diarylethenyl) alkanes via photoinduced electron transfer: Formation of bicyclic peroxides

T Tamai, K Mizuno, I Hashida, Y Otsuji

文献索引：Tamai, Toshiyuki; Mizuno, Kazuhiko; Hashida, Isao; Otsuji, Yoshio Tetrahedron Letters, 1993 , vol. 34, # 16 p. 2641 - 2644

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被引用次数: 13

摘要

Abstract The 9, 10-dicyanoanthracene (DCA)-sensitized photooxygenation of Ar 2 C= CH (CH 2) n CH= CAr 2 in acetonitrile was studied. When Ar= 4-CH 3 OC 6 H 4, n= 3 and 4, bicyclic peroxides were obtained via 1, 4-radical cations that are generated by intramolecular interaction between two ethenyl moieties of the alkadienes.