Aminimide derived from benzoylformic acid ester as photolatent base/radical initiator

M Kirino, I Tomita

文献索引：Kirino, Manabu; Tomita, Ikuyoshi Journal of Polymer Science, Part A: Polymer Chemistry, 2012 , vol. 50, # 8 p. 1556 - 1563

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被引用次数: 5

摘要

Abstract An aminimide possessing a benzoyl substituent, 1, 1-dimethyl-1-(2-hydroxypropyl) amine benzoylformimide (BFI), proved to serve as an excellent photobase catalyst. BFI decomposes smoothly by the UV irradiation to give products containing tertiary amines. The effective nature of BFI as a photo/thermal dual-base catalyst was convinced by the thermal and photoinduced polymerization of epoxide/thiol system. Based on the facts that the ...