Structure and spectral properties of dinuclear zinc complex containing semicarbazonate ligands

W Jing-Lin, F Jiao, X Mei-Ping, Y Bin-Sheng

文献索引：Jing-Lin, Wang; Jiao, Feng; Mei-Ping, Xu; Bin-Sheng, Yang Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2011 , vol. 78, # 4 p. 1245 - 1249

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被引用次数: 2

摘要

The dinuclear Zn2+ complex [Zn (HSSC) OAc] 2· 2DMF (H2SSC= salicylaldehyde semicarbazone; HOAc= acetic acid; DMF= N, N-dimethylfomamide) was prepared and structurally characterized by single crystal X-ray. The basic structural unit of the complex is a dinuclear complex [Zn (HSSC) OAc] 2 in which the semicarbazone ligand adopts the phenol- imine form. The deprotonated phenol group forms a one-atom bridge between the two ...