Asymmetric reactions. VI. Asymmetric reduction of ketimines by optically active alkoxy lithium aluminium hydrides

O Červinka, V Suchan, O Kotýnek…

文献索引：Cervinka,O. et al. Collection of Czechoslovak Chemical Communications, 1965 , vol. 30, p. 2484 - 2487

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被引用次数: 3

摘要

In previous communications, we studied asymmetric reduction of 1-methyl-2-alkyl-t.. 1- piperideinium perchlorates1, I-methyl-2-alkyl-t.. 1-pyrrolinium perchlorates2, methylalkyl ketones, methylaryl ketones3 and diaryl ketones4 by optically active alkoxy lithium aluminium hydrides; the reductive agents were prepared in situ by partial decomposition of lithium aluminium hydride with optically active alcohols. As reactions concerning carbonyl ...