A report describing the effect of di-2-pyridyl ligand architecture on the coordination properties with gold (III)

AS Hodges, SCY Lee, KI Hardcastle, MR Saadein…

文献索引：Hodges, Ashley S.; Lee, Suk Y.; Hardcastle, Kenneth I.; Saadein, M. Reza; Eichler, Jack F. Inorganica Chimica Acta, 2011 , vol. 368, # 1 p. 252 - 256

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被引用次数: 8

摘要

In an effort to develop novel gold-based chemotherapies, gold (III) coordination complexes possessing a series of di-2-pyridyl ligands were targeted as synthetic products. It was found that di-2-pyridyl ligands linked by different groups exhibited varying coordination to gold (III). Di-2-pyridyl sulfide (DPS) exhibited bidentate binding to gold (III), and formed a complex ion with a gold tetrachloride counter ion {[(DPS) AuCl2] AuCl4; compound 3}; di-2-pyridyl ...