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Chemistry Letters

Acetoxylation of Piperidine Derivatives at the 3-Position. Stereoselective Synthesis of Pseudoconhydrine and N-Methylpseudoconhydrine

…, Y Matsumura, O Onomura, T Kanazawa, M Habuka

文献索引:Shono, Tatsuya; Matsumura, Yoshihiro; Onomura, Osamu; Kanazawa, Takenobu; Habuka, Masahiro Chemistry Letters, 1984 , p. 1101 - 1104

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被引用次数: 15

摘要

Anodic oxidation of N-methoxycarbonylpiperidine derivatives in AcOH gave 2, 3- diacetoxylated products, which were shown to be useful intermediates for the stereoselective synthesis of 3-hydroxypiperidine derivatives including pseudoconhydrine and N-methylpseudoconhydrine, the Conium alkaloids.