Is there a homolytic substitution chemistry (SH2) of sulfones?

D Crich, TK Hutton, K Ranganathan

文献索引：Crich, David; Hutton, Thomas K.; Ranganathan, Krishnakumar Journal of Organic Chemistry, 2005 , vol. 70, # 19 p. 7672 - 7678

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被引用次数: 19

摘要

A series of 2-alkylsulfonyl-2'-biphenyl radicals, in which the alkyl group is primary, secondary, or tertiary, were generated and the products of their reactions investigated. Dibenzothiophene S, S-dioxide was not identified among the products, which arose mainly from intramolecular hydrogen abstraction from the alkyl group or addition to the solvent, benzene. On this basis, it is concluded that homolytic substitution at sulfonyl sulfur, if ...