Metal-catalyzed hydrosilylation of alkenes and alkynes using dimethyl (pyridyl) silane

…, K Mitsudo, A Nishino, J Yoshida

文献索引：Itami, Kenichiro; Mitsudo, Koichi; Nishino, Akira; Yoshida, Jun-Ichi Journal of Organic Chemistry, 2002 , vol. 67, # 8 p. 2645 - 2652

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被引用次数: 74

摘要

Metal-catalyzed hydrosilylation of alkenes and alkynes using dimethyl (pyridyl) silane is described. The hydrosilylation of alkenes using dimethyl (2-pyridyl) silane (2-PyMe2SiH) proceeded well in the presence of a catalytic amount of RhCl (PPh3) 3 with virtually complete regioselectivity. By taking advantage of the phase tag property of the 2-PyMe2Si group, hydrosilylation products were isolated in greater than 95% purity by simple acid- ...