Toxic Fluorine Compounds. VII. 1 ι-Fluoroalkyl Thiocyanates and ι-Fluoroalkyl Mercaptans

WC Howell, JE Millington…

文献索引：Howell et al. Journal of the American Chemical Society, 1956 , vol. 78, p. 3843,3845

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被引用次数: 7

摘要

Discussion According to the examples described in the Experimental part, the alcoholysis of an ester with an aluminum alcoholate can be brought to completion:(a) if the aluminum alcoholate produced in the reaction has a low solubility in the solvent in which the reaction is carried out, or (b) if the alcohol corresponding to the alkoxyl group to be exchanged is used as the solvent for the reaction. Reaction time is an important factor in the alkoxyl exchange ...