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The Journal of Organic Chemistry

Aerosol direct fluorination. Synthesis of perfluoroadamantane, the penultimate step

JL Adcock, ML Robin

文献索引:Adcock, J. L.; Robin, M. L. Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 3128 - 3130

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被引用次数: 17

摘要

Figure 1. difficulty of vacuum line transfers of the perfluorinated material also leads to significant losses in material isolated. Previously, fluorinations of adamantane and its substituted derivatives have resulted in significant ring opening. Lagow et al. have attributed this tendency to the fact that “As hydrogens are replaced by fluorine, the remaining positions become increasingly acidic, and the resultant tendency toward carbanion formation may ...