Activation of Aromatic, Aliphatic, and Olefinic Carbon–Fluorine Bonds Using Cp* 2HfH2

…, WW Brennessel, WD Jones

文献索引：Rieth, Ryan D.; Brennessel, William W.; Jones, William D. European Journal of Inorganic Chemistry, 2007 , # 18 p. 2839 - 2847

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被引用次数: 16

摘要

Abstract The hafnium hydride Cp* 2 HfH 2 is reacted with a series of fluorocarbons to examine the scope of C–F bond activation. Aromatic, vinylic, and aliphatic C–F bonds all show some degree of reactivity, and possible mechanisms are discussed.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)