Tetrahedron

Preparation et utilisation d'un synthon comportant un epoxyde chiral

J Soulie, M Lampilas, JY Lallemand

文献索引：Soulie, J.; Lampilas, M.; Lallemand, J. Y. Tetrahedron, 1987 , vol. 43, # 12 p. 2701 - 2708

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被引用次数: 11

摘要

A general method for the synthesis of chiral epoxides starting from the bifunctionalised epoxide synthon 2 is described. This approach is useful for the preparation of saturated epoxides. β, γ-unsaturated analogues could not be easily obtained. In this case, the use of metallic acetylides with BF3.(C2H5) 2O proved very helpful.