The Journal of Organic Chemistry

Stereospecific synthesis of Temarotene, its structural isomers, and mixed triaryl alkenes from gem-borazirconocene alkenes

L Deloux, M Srebnik, M Sabat

文献索引：Deloux, Laurent; Srebnik, Morris; Sabat, Michal Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3276 - 3277

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被引用次数: 30

摘要

The ability to form carbon-carbon bonds rationally around an alkene is the object of continuing vigorous research. l Our contribution to this area involves the use of gem- borazirconocene alkenes, 2, readily available from 1-alkynylboronates by hydrozirconation. 2 These compounds are stabile and due to the considerably different reactivities of the C-Zr and CB bonds, enable selective and sequential reactions with a variety of electrophiles. ...