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An efficient route to benzo [b] thiophenequinones, quinone bisketals, and quinone monoketals via anodic oxidation of methoxylated benzo [b] thiophenes. Studies …

BL Chenard, JR McConnell…

文献索引:Chenard, Bertrand L.; McConnell, J. Russell; Swenton, John S. Journal of Organic Chemistry, 1983 , vol. 48, # 23 p. 4312 - 4317

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被引用次数: 9

摘要

A convenient route to 4-and 7-methoxybenzo [b] thiophenes has been developed in the course of electrochemical studies of these molecules. The anodic oxidations of 4-methoxy-, 5-bromo-4-methoxy-, 5-methyl-4-methoxy-, and 6-bromo-7-methoxybenzo [blthiophene, 17a- d, respectively, in methanolic potassium hydroxide at a platinum anode have been investigated. The products obtained from the oxidation of these compounds were ...