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The influence of boryl substituents on the formation and reactivity of adjacent and vicinal free radical centers

JC Walton, AJ McCarroll, Q Chen…

文献索引:Journal of the American Chemical Society, , vol. 122, # 23 p. 5455 - 5463

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被引用次数: 34

摘要

... Journal ... Soc. , 2000, 122 (23), pp 5455–5463. DOI: 10.1021/ja9944812. Publication Date (Web): May 23, 2000. Copyright © 2000 American Chemical Society. ... 10 The vacant p-orbital on boron accepts a chemically significant amount of electron density from an adjacent π-system. ...