Journal of fluorine chemistry

The fluorination of butane over cobalt trifluoride

J Burdon, ST Ezmirly, TN Huckerby

文献索引：Burdon, James; Ezmirly, Saleh T.; Huckerby, Thomas N. Journal of Fluorine Chemistry, 1988 , vol. 40, p. 283 - 318

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被引用次数: 17

摘要

Abstract The fluorination of butane over cobalt trifluoride has given a complex mixture of partially fluorinated compounds: 51 of these have been identified, comprising over 99% of the products. Most were polyfluorobutanes but 1-2% were polyfluoro-2-methylpropanes. The reaction has no synthetic utility. There was some selectivity in the fluorination: secondary CH was converted into CF more easily then primary, and the ease of replacement of a ...