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Multiple pathways in cyclodextrin-catalyzed hydrolysis of perfluoroalkylamides

A Granados, RH de Rossi

文献索引:Granados, Alejandro; De Rossi, Rita H. Journal of the American Chemical Society, 1995 , vol. 117, # 13 p. 3690 - 3696

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被引用次数: 36

摘要

Abstract: The hydrolysis of p-nitroanilide of perfluoroalkanoic acids, CF3 (CF2),, CO-, with n= 1, 2, 3, 5, 6, and 7, la-f, was studied in the presence of P-cyclodextrin (CD). All reactions were catalyzed by CD through the formation of a 1: l and 1: 2 inclusion complexes. The association equilibrium constants for the 1: l complexes were dependent on the number of carbons of the fluoroalkyl chain, whereas those of the 1: 2 complexes were almost ...