Chemical Communications

Gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen. Simultaneous degradation of C–H and single and triple carbon–carbon …

A Das, R Chaudhuri, RS Liu

文献索引：Das, Arindam; Chaudhuri, Rupsha; Liu, Rai-Shung Chemical Communications, 2009 , # 27 p. 4046 - 4048

全文：HTML全文

被引用次数: 17

摘要

The metal-catalyzed cleavage of a carbon–carbon triple bond has stimulated new conceptual strategies in organic synthesis. 1,2 The use of oxygen to cleave a carbon–carbon bond catalytically is economically and environmentally important. Although the catalytic cleavage of C–C and C C bonds using oxygen as the oxidant has achieved reasonable progress, 3 very limited examples have been documented for the oxygen-induced oxidative cleavage of a C C bond. 2d,e ...