Oxidative photo-decarboxylation in the presence of mesoporous silicas

A Itoh, T Kodama, Y Masaki, S Inagaki

文献索引：Itoh, Akichika; Kodama, Tomohiro; Masaki, Yukio; Inagaki, Shinji Chemical and Pharmaceutical Bulletin, 2006 , vol. 54, # 11 p. 1571 - 1575

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被引用次数: 18

摘要

FSM-16, a mesoporous silica, was found to catalyze oxidative photo-decarboxylation of α- hydroxy carboxylic acid, phenyl acetic acid derivatives and N-acyl-protected α-amino acids to afford the corresponding carbonyl compounds. Furthermore, FSM-16 proved to be re- usable by re-calcination at 450° C after the reaction.