Broadly applicable bifunctional synthetic building blocks are of high value not only for the preparation of single molecules but also for the modular assembly of structurally diverse compound libraries.[1] Along the lines of our recent work in the field of aryl radical chemistry,[2, 3] we turned our interest towards derivatives of benzene, in which the aromatic core could be selectively modified by a nucleophilic substitution [4–7] as well as by a ...