Tetrahedron letters

Co (salen) catalyzed oxidation of 2, 4, 6-trisubstituted anilines with tert-butylhydroperoxide

A Nishinaga, S Fo, E Eichhorn, B Speiser, A Rieker

文献索引：Nishinaga; Forster; Eichhorn; Speiser; Rieker Tetrahedron Letters, 1992 , vol. 33, # 31 p. 4425 - 4428

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被引用次数: 18

摘要

Abstract Co (salen) catalyzed oxidation of 2, 4, 6-trisubstituted (preferentially 2, 6-di-tert- butylated) anilines withtert-butylhydroperoxide gives 4-tert-butylperoxy-2, 5-cyclohexadien-1- imine and nitrobenzene derivatives. The relative ratio of the products depends on the nature of the substituents in the substrate.