Tetrahedron

Influence of catalytic system composition on formation of adamantane containing ketones

R Vícha, M Potáček

文献索引：Vicha, Robert; Potacek, Milan Tetrahedron, 2005 , vol. 61, # 1 p. 83 - 88

被引用次数: 13

摘要

The preparation of non-symmetrical ketones by the reaction of acyl chlorides and the corresponding Grignard reagents in the presence of catalytic amounts of metal halides is described. The composition of catalyst has a great influence on the yield of the required ketone as well as on side product formation. For each catalytic system, the yield of ketone and the number of side products changes with the time of addition of the Grignard reagent. ...

~86%

~93%

~90%

~69%

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