Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

RI Khusnutdinov, NA Schchadneva, AI Malikov…

文献索引：Khusnutdinov; Schchadneva; Malikov; Dzhemilev Petroleum Chemistry, 2006 , vol. 46, # 3 p. 159 - 163

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摘要

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.