ICl-Mediated Intramolecular Twofold Iodoarylation of Diynes and Diynyl Diethers and Amines: Synthesis of Bis (2 H-hydronaphthalene and chromene) and 2 H- …
J Mo, W Choi, J Min, CE Kim, D Eom…
文献索引：Mo, Juntae; Choi, Wonseok; Min, Jiae; Kim, Cheol-Eui; Eom, Dahan; Kim, Sung Hong; Lee, Phil Ho Journal of Organic Chemistry, 2013 , vol. 78, # 22 p. 11382 - 11388
Electrophilic intramolecular twofold iodoarylation was developed from the reaction of diynes and diynyl diethers and amines with iodine monochloride under mild conditions, which produced bis (2 H-hydronaphthalene and chromene) and 2 H-quinoline bearing an alkenyl iodide moiety in good to excellent yields. These compounds underwent Pd-catalyzed cross- coupling reactions with arylboronic acid and indium tris (arylthiolate) to produce the ...
