Australian Journal of Chemistry

Mixed carboxylate sulphonate esters of glycerol

SC Auteri, DW Cameron

文献索引：Auteri,S.C.; Cameron,D.W. Australian Journal of Chemistry, 1977 , vol. 30, p. 2487 - 2492

全文：HTML全文

被引用次数: 1

摘要

Abstract Syntheses of the four mixed palmitate p-toluenesulphonate triesters of glycerol are described. Syntheses involving p-toluenesulphonic acid were in some cases accompanied by acyl migration. This was avoided by the use of p-toluenesulphonyl chloride in pyridine. The products were analysed by pmr spectra in the presence of europium shift reagent. They underwent smooth reductive cleavage of p-toluenesulphonate on treatment with sodium ...