Unusual OC sp 2 Bond Cleavage in Vinyl Ethers with Organylhalosilanes

SV Basenko, EV Boyarkina, MG Voronkov

文献索引：Basenko; Boyarkina; Voronkov Russian Journal of General Chemistry, 2003 , vol. 73, # 3 p. 488 - 489

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被引用次数: 2

摘要

For example, the reaction of butyl vinyl ether with trichloro (phenyl) silane at a 1: 1 molar ratio at 20oC gives vinyl chloride and dichloro (butoxy) phenylsilane in a near-quantitative yield (96%). At 2: 1 and 3: 1 reagent molar ratios, a mixture of chloro (butoxy)-phenylsilanes PhSi (OBu) 3! nCln (n= 032) is formed. The major component of the mixture is dichloro (butoxy) phenylsilane.