Angewandte Chemie International Edition

Rearrangement of 2??Aryloxybenzaldehydes to 2??Hydroxybenzophenones by Rhodium??Catalyzed Cleavage of Aryloxy C O Bonds

H Rao, CJ Li

文献索引：Rao, Honghua; Li, Chao-Jun Angewandte Chemie - International Edition, 2011 , vol. 50, # 38 p. 8936 - 8939

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被引用次数: 16

摘要

The catalytic cleavage and functionalization of CÀO bonds offer great potential for the utilization of biomass (eg, carbohydrates and lignins) as renewable chemical feedstocks,[1] and broadening the diversity of functional molecules in the manufacture of pharmaceuticals and fine chemicals through the direct functionalization of alkyloxy-and aryloxycontaining natural products.[2] For transition-metal-catalyzed CÀC bond formation by CArÀO bond ...